NDAs cannot cover whistleblowing of actual criminality, including sexual harassment, which is why modern NDAs take pains to disclaim that, so they wouldn't be invalidated on that basis. Presumably the behavior exposed in the book, while arguably immoral or amoral, doesn't rise to the standard of criminality.
Ms Wynn-Williams has also filed a whistleblower complaint with the US markets regulator, the Securities and Exchange Commission (SEC), alleging Meta misled investors - which Meta also denies. The BBC has reviewed the complaint.
That said, arbitrators like that which gagged her are inherently conflicted since they are paid by the corporation, sadly our corrupt Supreme Court rubber-stamped binding arbitration so she has no recourse.